Organoneptunium chemistry

Chemistry of organometallic compounds containing an neptunium-carbon bond

Organoneptunium chemistry is the chemical science exploring the properties, structure, and reactivity of organoneptunium compounds, which are organometallic compounds containing a carbon to neptunium chemical bond.[1] Several such compounds exist even though the element itself, neptunium, is man-made and highly radioactive: tricyclopentadienylneptunium-chloride,[2][3] tetrakis(cyclopentadienyl)neptunium(IV)[4] and neptunocene Np(C8H8)2.

See also

  • Organoactinide chemistry

References

  1. ^ Organometallic Neptunium Chemistry Polly L. Arnold, Michał S. Dutkiewicz, and Olaf Walter Chemical Reviews Article ASAP doi:10.1021/acs.chemrev.7b00192
  2. ^ Über die Existenz von Tri-cyclopentadienyl-neptunium(IV)-halogenid F. BaumgärtnerE. O. FischerP. Laubereau Naturwissenschaften January 1965, Volume 52, Issue 20, pp 560–560 doi:10.1007/BF00631569
  3. ^ Tricyclopentadienylneptunium-chlorid E.O.Fischer P.Laubereau F.Baumgärtner B.Kanellakopulos Journal of Organometallic Chemistry Volume 5, Issue 6, June 1966, Pages 583-584 doi:10.1016/S0022-328X(00)85165-7
  4. ^ Baumgärtner, F., Fischer, E. O., Kanellakopulos, B. and Laubereau, P. (1968), Tetrakis(cyclopentadienyl)neptunium(IV). Angew. Chem. Int. Ed. Engl., 7: 634. doi:10.1002/anie.196806341
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Compounds of carbon with other elements in the periodic table
CH He
CLi CBe CB CC CN CO CF Ne
CNa CMg CAl CSi CP CS CCl CAr
CK CCa CSc CTi CV CCr CMn CFe CCo CNi CCu CZn CGa CGe CAs CSe CBr CKr
CRb CSr CY CZr CNb CMo CTc CRu CRh CPd CAg CCd CIn CSn CSb CTe CI CXe
CCs CBa 1 asterisk CLu CHf CTa CW CRe COs CIr CPt CAu CHg CTl CPb CBi CPo CAt Rn
Fr CRa 2 asterisks Lr Rf Db CSg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
1 asterisk CLa CCe CPr CNd CPm CSm CEu CGd CTb CDy CHo CEr CTm CYb
2 asterisks Ac CTh CPa CU CNp CPu CAm CCm CBk CCf CEs Fm Md No
Legend
  • Chemical bonds to carbon
  • Core organic chemistry
  • Many uses in chemistry
  • Academic research, no widespread use
  • Bond unknown


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