Iodide hydride
Iodide hydrides are mixed anion compounds containing hydride and iodide anions. Many iodide hydrides are cluster compounds, containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.
List
| formula | system | space group | unit cell Å | volume | density | comment | reference |
|---|---|---|---|---|---|---|---|
| (DippNacnac)Mg(μ-H)(μ-I)Mg(MesNacnac) | [1] | ||||||
| KHI | [2][3] | ||||||
| [LZnI(η2-H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidine | [4] | ||||||
| Sr2H3I | trigonal | P3m1 | a = 4.260 c = 7.749 Z=1 | 121.77 | 4.16 | transparent | [5] |
| YIH | C=31.033 | metallic | [6] | ||||
| YIH2 | P3m1 | a = 3.8579, c = 10.997 | light green | [6] | |||
| Nb6I11H | D10/2h | a = 11.317; b = 15.471 ; c = 13.431 | [7] | ||||
| Nb6I11H | Im3m | a = 11.317; b = 15.471 ; c = 13.431 | black | [7] | |||
| Nb6(H)I9S | triclinic | P1 | a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2 | [8][9] | |||
| HCsNb6I11 | [10] | ||||||
| Ba2H3I | trigonal | P3m1 | a= 4.519 c= 8.1184 | transparent | [11] | ||
| Ba5H2I4O2 | orthorhombic | Cmcm | a =17.210, b = 14.525 c = 6.3903 Z=4 | 1597.44 | 5.11 | transparent | [5] |
| LaI2H | hexagonal | P63/mmc | a=4.2158 c=15.508 | [12][13] | |||
| NdI2H | [14] | ||||||
| Gd2ICH0.73 | P63mc | a=3.8128 C=14.844 Z=2 | 8.071 | [15] | |||
| Eu2H3I | dark red | [16] | |||||
| Eu5H2O2I4 | orthorhombic | Cmcm | a = 16.3697, b = 13.6954, c = 6.0436, Z = 4 | dark red | [16] | ||
| Tb2ICH | [15] | ||||||
| DyI2H | [14] | ||||||
| [(η5-C5H5)W(NO)IH]2 | [17] | ||||||
| (η5-C5H5)W(NO)I(H)(P(OPh)3) | |||||||
| Ir(η2-H2)(H)2I(PiPr3)2 | [18][19] | ||||||
| Ir(η2-H2)(H)2I(PiPr3)2•C10H8 | triclinic | P1 | a=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=2 | 15K | [19] |
References
- ^ Jones, Cameron; Stasch, Andreas (2013), Harder, Sjoerd (ed.), "Stable Molecular Magnesium(I) Dimers: A Fundamentally Appealing Yet Synthetically Versatile Compound Class", Alkaline-Earth Metal Compounds, Topics in Organometallic Chemistry, vol. 45, Berlin, Heidelberg: Springer Berlin Heidelberg, pp. 73–101, doi:10.1007/978-3-642-36270-5_3, ISBN 978-3-642-36269-9, retrieved 2023-11-15
- ^ Mills, R (November 2001). "Minimum heat of formation of potassium iodo hydride". International Journal of Hydrogen Energy. 26 (11): 1199–1208. doi:10.1016/S0360-3199(01)00051-9.
- ^ Mills, R (December 2000). "Synthesis and characterization of potassium iodo hydride". International Journal of Hydrogen Energy. 25 (12): 1185–1203. doi:10.1016/S0360-3199(00)00037-9.
- ^ Lummis, Paul Ashley (2015). Earth-Abundant Transition Metal Hydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis. University of Alberta.
- ^ a b Reckeweg, Olaf; DiSalvo, Francis J. (2011-01-01). "AlkalineEarthMetal-Hydride-Iodide Compounds: Syntheses andCrystal Structures of Sr 2 H 3 I and Ba 5 H 2 I 3.9(2) O 2". Zeitschrift für Naturforschung B. 66 (1): 21–26. doi:10.1515/znb-2011-0104. ISSN 1865-7117. S2CID 27301598.
- ^ a b Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (August 2004). "YIH n : A New Family of Metal-rich Hydride Halides". Zeitschrift für anorganische und allgemeine Chemie. 630 (10): 1401–1407. doi:10.1002/zaac.200400094. ISSN 0044-2313.
- ^ a b Simon, Arndt (December 1967). "Beiträge zur Chemie der Elemente Niob und Tantal. LXV. HNb6J11 Eine Verbindung mit der komplexen Gruppe [HNb6J8]". Zeitschrift für anorganische und allgemeine Chemie. 355 (5–6): 311–322. doi:10.1002/zaac.19673550511.
- ^ Meyer, H. Juergen; Corbett, John D. (October 1992). "Theoretical study of the electronic properties of niobium iodide sulfide (Nb6I9S) and its hydride (Nb6(H)I9S)". Inorganic Chemistry. 31 (21): 4276–4280. doi:10.1021/ic00047a013. ISSN 0020-1669.
- ^ Meyer, H. Juergen; Corbett, John D. (March 1991). "Synthesis and structure of the novel chain compound niobium iodide sulfide (Nb6I9S) and its hydride". Inorganic Chemistry. 30 (5): 963–967. doi:10.1021/ic00005a017. ISSN 0020-1669.
- ^ Simon, Arndt (March 1985). "Empty, filled, and condensed metal clusters". Journal of Solid State Chemistry. 57 (1): 2–16. Bibcode:1985JSSCh..57....2S. doi:10.1016/S0022-4596(85)80055-4.
- ^ Reckeweg, Olaf; DiSalvo, Francis J. (2011-11-01). "Filling up another Gap: Synthesis and Crystal Structure of Ba 2 H 3 I". Zeitschrift für Naturforschung B. 66 (11): 1087–1091. doi:10.1515/znb-2011-1101. ISSN 1865-7117. S2CID 40246199.
- ^ Imoto, Hideo; Corbett, John D. (February 1981). "Lanthanum and neodymium diiodide hydride phases and their hydrogen dissociation pressures". Inorganic Chemistry. 20 (2): 630–633. doi:10.1021/ic50216a062. ISSN 0020-1669.
- ^ Ryazanov, M; Simon, A; Mattausch, Hj; Kremer, R.K (July 2004). "The structural change of lanthanum diiodide upon hydrogenation". Journal of Alloys and Compounds. 374 (1–2): 142–145. doi:10.1016/j.jallcom.2003.11.072.
- ^ a b Bochkarev, M. N.; Logunov, A. A.; Burin, M. E. (October 2007). "Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H". Russian Chemical Bulletin. 56 (10): 1953–1955. doi:10.1007/s11172-007-0303-x. ISSN 1066-5285. S2CID 93943595.
- ^ a b Ruck, M.; Simon, A. (November 1992). "Ln2XCHy: Kondensierte Cluster mit zwei verschiedenen interstitiellen Atomen". Zeitschrift für anorganische und allgemeine Chemie (in German). 617 (11): 7–18. doi:10.1002/zaac.19926170102. ISSN 0044-2313.
- ^ a b Rudolph, Daniel; Wylezich, Thomas; Netzsch, Philip; Blaschkowski, Björn; Höppe, Henning A.; Goldner, Philippe; Kunkel, Nathalie; Hoslauer, Jean-Louis; Schleid, Thomas (2023-10-07). "Synthesis and Crystal Structure of the Europium(II) Hydride Oxide Iodide Eu5H2O2I4 Showing Blue-Green Luminescence". International Journal of Molecular Sciences. 24 (19): 14969. doi:10.3390/ijms241914969. ISSN 1422-0067. PMC 10573458. PMID 37834417.
- ^ Oxley, Jimmie Carol (20 April 1978). Nitrosyl Hydrides and Cations of Group VI Transition Metals. California State University Northridge.
- ^ Bau, Robert; Drabnis, Mary H. (June 1997). "Structures of transition metal hydrides determined by neutron diffraction". Inorganica Chimica Acta. 259 (1–2): 27–50. doi:10.1016/S0020-1693(97)89125-6.
- ^ a b Eckert, Juergen; Jensen, Craig M.; Koetzle, Thomas F.; Husebo, Trang Le; Nicol, Jacqueline; Wu, Ping (July 1995). "Inelastic Neutron Scattering Studies of IrIH2(H2)(PPri3)2 and Neutron Diffraction Structure Determination of IrIH2(H2)(PPri3)2•C10H8: Implications on the Mechanism of the Interconversion of Dihydrogen and Hydride Ligands". Journal of the American Chemical Society. 117 (27): 7271–7272. doi:10.1021/ja00132a038.
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Salts and covalent derivatives of the iodide ion
| HI +H | He | |||||||||||||||||
| LiI | BeI2 | BI3 +BO3 | CI4 +C | NI3 NH4I +N | I2O4 I2O5 I4O9 | IF IF3 IF5 IF7 | Ne | |||||||||||
| NaI | MgI2 | AlI AlI3 | SiI4 | PI3 P2I4 +P PI5 | S2I2 | ICl ICl3 | Ar | |||||||||||
| KI | CaI2 | ScI3 | TiI2 TiI3 TiI4 | VI2 VI3 | CrI2 CrI3 | MnI2 | FeI2 FeI3 | CoI2 | NiI2 -Ni | CuI | ZnI2 | GaI GaI3 | GeI2 GeI4 +Ge | AsI3 As2I4 +As | Se | IBr IBr3 | Kr | |
| RbI RbI3 | SrI2 | YI3 | ZrI2 ZrI3 ZrI4 | NbI4 NbI5 | MoI2 MoI3 | TcI3 | RuI3 | RhI3 | PdI2 | AgI | CdI2 | InI InI3 | SnI2 SnI4 | SbI3 +Sb | TeI4 +Te | I− I− 3 | Xe | |
| CsI CsI3 | BaI2 | LuI3 | HfI3 HfI4 | TaI4 TaI5 | WI2 WI3 WI4 | ReI3 ReI 4 | OsI OsI2 OsI3 | IrI3 IrI 4 | PtI2 PtI4 | AuI AuI3 | Hg2I2 HgI2 | TlI TlI3 | PbI2 | BiI3 | PoI2 PoI4 | AtI | Rn | |
| Fr | RaI2 | Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | ||||||||||||||||||
| LaI2 LaI3 | CeI2 CeI3 | PrI2 PrI3 | NdI2 NdI3 | PmI3 | SmI2 SmI3 | EuI2 EuI3 | GdI2 GdI3 | TbI3 | DyI2 DyI 3 | HoI3 | ErI3 | TmI2 TmI3 | YbI2 YbI3 | |||||
| AcI3 | ThI2 ThI3 ThI4 | PaI4 PaI5 | UI3 UI4 | NpI3 | PuI3 | AmI2 AmI3 | CmI3 | BkI 3 | CfI 2 CfI 3 | EsI2 EsI3 | Fm | Md | No | |||||
