Deuterated DMF : Wikipedia, the free encyclopedia

Deuterated DMF

Names

IUPAC name

1-Deuterio-N,N-bis(trideuteriomethyl)formamide^{[citation needed]}

Other names

Dimethylformamide-d₇^{[citation needed]}
N,N-Dimethylformamide-d₇^{[citation needed]}
Heptadeutero-N,N-dimethylformamide^{[citation needed]}

Identifiers

CAS Number

4472-41-7^Y

3D model (JSmol)

Interactive image

Abbreviations

DMF-d₇^{[citation needed]}

Beilstein Reference

1908468

ChemSpider

70601^N

ECHA InfoCard

100.022.497

EC Number

224-745-8

PubChem CID

78225

UN number

2265

CompTox Dashboard (EPA)

DTXSID30196283

InChI

InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D^N
Key: ZMXDDKWLCZADIW-YYWVXINBSA-N^N

SMILES

[2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]

Properties

Chemical formula

C
₃²
H
₇NO or C
₃D
₇NO

Molar mass

80.1369 g mol⁻¹

Appearance

Colourless liquid

Density

1.03 g mL⁻¹

Boiling point

153 °C (307 °F; 426 K)

Refractive index (n_D)

1.428

Hazards

GHS labelling:

Pictograms

Signal word

Danger

Hazard statements

H312, H319, H332, H360

Precautionary statements

P280, P305+P351+P338, P308+P313

Flash point

58 °C (136 °F; 331 K)

Explosive limits

2.2–15.2%

Lethal dose or concentration (LD, LC):

LD₅₀ (median dose)

2.8 g kg⁻¹ (oral, rat)
1.5–4.72 g kg⁻¹ (dermal, rabbit)

Related compounds

Related alkanamides

N-Methylformamide
Dimethylformamide

Related compounds

N-Nitroso-N-methylurea
ENU

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

N verify (what is ^YN ?)

Infobox references

Chemical compound

Deuterated dimethylformamide ((CD₃)₂NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH₃)₂NCOH) in which the hydrogen atom ("H") is replaced with a deuterium isotope ("D"). Deuterated DMF is a relatively uncommon solvent used in NMR spectroscopy.^[1]^[2]

References

^ Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation". Macromolecules. 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297.
^ Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution". New Journal of Chemistry. 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. S2CID 132588760.